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61.
By variational methods, for a kind of Webster scalar curvature problems on the CR sphere with cylindrically symmetric curvature, we construct some multi-peak solutions as the parameter is sufficiently small under certain assumptions. We also obtain the asymptotic behaviors of the solutions. 相似文献
62.
《中国化学快报》2021,32(8):2359-2368
The photoisomerization properties of azo derivatives have been widely used in the fields of materials and biology.One serious restriction to the development of functional azo-based materials is the necessity to trigger switching by UV light,which damage the corresponding surfaces and penetrate only partially through the matter.Therefore,developing the visible and near-infrared light activated azo switches can solve this problem.This review provides a summary of molecular design strategies for driving the isomerization of azo derivatives with visible light and near-infrared light:(1) smart design directly excited by visible light,(2) the addition of upconversion nanoparticles,(3) the employment of twophoton absorption,(4) indirect excitation in combination with metal sensitizer. 相似文献
63.
In this study, a porous polypropylene frit was coated with polydimethylsiloxane (PDMS) as extraction medium, based on the home-made PDMS-frit, a rapid, simple and sensitive sorptive extraction method was established for analysis of potential biomarkers of lung cancer (hexanal and heptanal) in human serum samples. In the method, derivatization and extraction occurred simultaneously on the PDMS-frit, then the loaded frit was ultrasonically desorbed in acetonitrile. Polymerization, derivatization–extraction and desorption conditions were optimized. Under the optimal conditions, satisfactory results were gained, a wide linear application range was obtained in the range of 0.002–5.0 μmol L−1 (R > 0.997) for two aldehydes, the detection limits (S N−1 = 3) were 0.5 nmol L−1 for hexanal and 0.4 nmol L−1 for heptanal. The relative standard deviations (RSDs, n = 5) of the method were below 7.9% and the recoveries were above 72.7% for the spiked serum. All these results hint that the proposed method is potential for disease markers analysis in complex biological samples. 相似文献
64.
65.
Yu Zhang Lei Jiao Weiqing Xu Yifeng Chen Yu Wu Hongye Yan Wenling Gu Chengzhou Zhu 《中国化学快报》2022,33(3):1317-1320
Although carbon nanozymes have attracted great interest due to their good biocompatibility, low cost,and high stability, designing high-active carbon nanozymes still faces great challenges. Herein, ultrathin nitrogen-doped carbon nanosheets with rich defects(d-NC) were prepared through a high-temperature annealing process, using potassium chloride and ammonium chloride as templates. Owing to the large specific surface area, rich defects and the high exposure of active sites, the proposed d-NC na... 相似文献
66.
67.
To improve contrast between dim target region and background in infrared (IR) long-range surveillance, this paper proposes a fast image enhancement approach using saliency feature extraction based on multi-scale decomposition. Firstly, a smooth based multi-scale decomposition is designed and applied to original infrared image, generating sub-images with various frequency components at different decomposition levels. The dim target regions of sub-images are extracted by a local frequency-tuned based saliency feature detection method, secondly. With saliency maps created by saliency extraction using multi-scale local windows with different sizes, the sub-images are enhanced at different decomposition scales. Finally, the enhanced result is reconstructed by synthesizing the all sub-images with adjustable synthetic weights. Since salient areas are analyzed based on fast multi-scale image decomposition, IR image can be s enhanced with good contrast successfully and rapidly. Compared with other algorithms, the experimental results prove that the proposed method is robust and efficient for IR image enhancement. 相似文献
68.
In this study, we developed a novel ultrasound-assisted electrocatalytic oxidation (US–EO) process to decolorize azo dyes in aqueous solution. Rhodamine B was decolorized completely within several minutes in this developed US–EO system. Oxidation parameters such as applied potentials, power of the ultrasound, initial pH of the solution, and initial concentration of RhB were systematically studied and optimized. An obvious synergistic effect was found in decolorization of RhB by the US–EO process when comparing with either ultrasound (US) process or electrocatalytic oxidation (EO) one. Additionally, the decolorization of other azo dyes, such as methylene blue, reactive brilliant red X-3B, and methyl orange, were also effective in the US–EO system. The results indicated that US–EO system was effective for the decolorization of azo dyes, suggesting its great potential in dyeing wastewater treatment. 相似文献
69.
Yan YangMeng Gao Liu-Ming WuCong Deng Dong-Xue ZhangYang Gao Yan-Ping ZhuAn-Xin Wu 《Tetrahedron》2011,67(29):5142-5149
The convergent and linear domino reactions have been first integrated, for the first time, to provide an efficient synthesis of indole-furan conjugates from indoles, methyl ketones, and 1,3-dicarbonyl compounds. 相似文献
70.
Yu Chen Hua Fan Guang‐Zhong Yang Yan Jiang Fang‐Fang Zhong Hong‐Wu He 《Helvetica chimica acta》2011,94(4):662-668
A new xanthone derivative, garcinexanthone F ( 1 ), which was found to possess an α,β‐unsaturated γ‐lactone moiety, and a new bisxanthone, bigarcinenone B ( 2 ), with a terpene bridge providing the xanthone? xanthone linkage, were isolated from the bark of Garcinia xanthochymus. Their structures were elucidated by spectroscopic methods, especially 2D‐NMR techniques. The antioxidant assay in vitro showed that compounds 1 and 2 exhibited significant scavenging activities against 1,1‐diphenyl‐2‐picrylhydrazyl (DPPH) radical with IC50 values of 22.32 and 20.14 μM , and against HO. radical with IC50 values of 1.16 and 2.85 μM , respectively. 相似文献